2.1 Chemistry Tutorial

The chemical compounds that are important for understanding most of the chemistry in this course are organic - that means that the compounds primarily contain carbon, hydrogen, and oxygen atoms (also sulfur and nitrogen). They can also be called hydrocarbons. The basic structures that we will be discussing in this course are called: 1) alkane (aka aliphatic), 2) branched alkane, 3) cycloalkane, 4) alkenes (double-bonds), 5) aromatic, 6) hydroaromatic, and 7) alcohols. First, I will show the atoms and how they are connected using the element abbreviation and lines as bonds, and then I will show abbreviated structural representations.

1. Alkane - atoms are lined up. For stick representation, each corner represents a CH2 group, and each end represents a CH3 group.
NameAtoms and BondsStick Representation
Heptane (7 C atoms)Heptane Chemical StructureHeptane drawing
2. Branched Alkane - still an alkane, but instead of a straight line, the carbons are branched off of each other.
NameAtoms and BondsStick Representation
Isobutane (4 C atoms)Istobutane chemical structureIsobutane drawing

 

Isopentane (5 C atoms)Isopentane chemical structureIsopentane drawing
3. Cycloalkanes - again, still an alkane, but forms a ring compound.
NameAtoms and BondsStick Representation
Cyclohexane (6 C atoms)Cyclohexane chemical structureCyclohexane drawing
4. Alkenes - alkanes that contain a double bond.
NameAtoms and BondsStick Representation
Pentene (5 C atoms)Pentene Chemical StructurePentene drawing
5. Aromatic - hydrocarbon ring compound with single and double bonds, significant differences in properties.
NameAtoms and BondsStick Representation
Benzene (6 C atoms)Benzene chemical structureBenzene drawing
6. Hydroaromatics - hydrocarbon ring compound with an aromatic and an alkane in one molecule.
NameAtoms and BondsStick Representation
1,2,3,4-tetrahydronaphthalene, aka tetralin (10 C atoms)Tetralin Chemical StructureTetraliln drawing
7. Alcohols - hydrocarbon with -OH functional group.
NameAtoms and BondsStick Representation
Butanol (4 C atoms)Butanol Chemical StructureButanol drawing
Ethanol (2 C atoms)Ethanol Chemical StructureEthanol drawing

The following table shows common hydrocarbons and their properties. It is important to know the properties of various hydrocarbons so that we can separate them and make chemical changes to them. This is a very brief overview - we will not yet be going into significant depth as to why the differences in chemicals affect the properties.

List of Common Hydrocarbons and Properties
NameNumber of C AtomsMolecular Formula

bp

(°C), 1 atm

mp

(°C)

Density

(g/mL) (@20°C)

Methane1CH4-161.5-182--
Ethane2C2H6-88.6-183--
Propane3C3H8-42.1-188--
Butane4C4H10-0.5-138--
Pentane5C5H1236.1-1300.626
Hexane6C6H1468.7-950.659
Heptane7C7H1698.4-910.684
Octane8C8H18125.7-570.703
Nonane9C9H20150.8-540.718
Decane10C10H22174.1-300.730
Tetradecane14C14H30253.560.763
Hexadecane16C16H34287180.770
Heptadecane17C17H36303220.778
Eicosane20C20H4234336.80.789
Cyclohexane6C6H12816.50.779
Cyclopentane5C5H1049-940.751
Ethanol2C2H6O78-1140.789
Butanol4C4H10O118-900.810
Pentene5C5H1030-1650.640
Hexene6C6H1263-1400.673
Benzene6C6H680.15.50.877
Naphthalene10C10H8218801.140
1,2,3,4-Tetrahydronaphthalene10C10H12207-35.80.970